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  • 产品名称：PBDD4T-2F BDD4T-2F PBDD-ff4T

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简单介绍：
High purity and high molecular weight - PBDD4T-2F is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere - polymer at its pure best Batch-specific GPC data - so you have confidence in what you are ordering. Also, GPC data is always convenient for your thesis and publications
详情介绍：

Luminosyn™ PBDD4T-2F is now available, featuring:

  • High purity and high molecular weight - PBDD4T-2F is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere - polymer at its pure best
  • Batch-specific GPC data - so you have confidence in what you are ordering. Also, GPC data is always convenient for your thesis and publications
  • Large-quantity orders - so you can plan your experiments with polymers from the same batch

Pricing

Batch Quantity
M2050A1 100 mg
M2050A1 250 mg
M2050A1 500 mg
M2050A1 1 g
M2050A1 5 - 10 g*

  *for 5-10 grams order quantity, the lead time is 4-6 weeks.

Batch details

Batch Mw Mn PDI
M2050A1 138,330 53,285 2.60

 

General Information

Full name Poly[[5,7-bis(2-ethylhexyl)-4,8-dioxo-4H,8H-benzo[1,2-c:4,5-c']dithiophene-1,3-diyl][3,3'''-bis(2-ethylhexyl)-3'',4'-difluoro[2,2':5',2'':5'',2'''-quaterthiophene]-5,5'''-diyl]]
Synonyms BDD4T-2F, PBDD-ff4T
Chemical formula (C58H72F2O2S6)n
CAS number 1890205-85-2
HOMO / LUMO HOMO = -5.39 eV, Eg = 1.76 eV [1]
Classification / Family Polythiophenes, Organic n-type semiconducting materials, Organic Photovoltaics, Polymer solar cells, Tandem Solar Cells, Electron-acceptor polymers, OFETs, Perovskite solar cells, All-polymer solar cells.
Suggesting solvents Chlorobenzene, dichlorobenzene
pbdd4t-2f, chemical structure
Chemical structure and product image of PBDD4T-2F; Chemical formula: (C58H72F2O2S6)n.

Applications

PBDD4T-2F polymer semiconductor has been developed for OPV applications (including both fullerene and non-fullerene polymer solar cells) and has an efficiency of over 9% [1]. It has been built into tandem solar cells, and PCE reaching 13% was reported with the following structure: PBDD4T-2F:PC71BM (front cell) & PBDTTT-E-T:IEICO (rear cell) [2].

When compared to PBDD4T, PBDD4T-2F has a stronger tendency to aggregate in solution. It also has a stronger π–π stacking compact in solid thin-film, and shows a deeper HOMO energy level of -5.39 eV.

PBDD4T-2F finds application in both fullerene and NFAs such as ITIC and P(NDI2OD-T2) polymer solar cells with highly efficient device performances.

Literature and Reviews

  1. A Fluorinated Polythiophene Derivative with Stabilized Backbone Conformation for Highly Efficient Fullerene and Non-Fullerene Polymer Solar Cells, S. Zhang et al., Macromolecules, 49 (8), 2993–3000 (2016); DOI: 10.1021/acs.macromol.6b00248.
  2. Achieving 12.8% Efficiency by Simultaneously Improving  Open-Circuit Voltage and Short-Circuit Current Density in Tandem Organic Solar Cells, Y. Qin et al., Adv. Mater., 29, 1606340 (2017); DOI: 10.1002/adma.201606340.
  3. Over 11% Efficiency in Tandem Polymer Solar Cells Featured by a Low-Band-Gap Polymer with Fine-Tuned Properties, Z. Zheng, Adv. Mater., 28, 5133–5138 (2016); DOI: 10.1002/adma.201600373.
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